Which James Bond film was the first to feature a duet as its theme song?

"Another Way to Die" is a song by American rock musician and singer Jack White and American R&B singer Alicia Keys. Written and produced by White as the theme song to the 2008 James Bond film Quantum of Solace, it was released as a single in the United States on September 30, 2008 and in Europe on October 20, 2008. The song is the first single from As I Am: The Super Edition.

The song which features White on vocals, guitar and drums and Keys on vocals is the first duet in the Bond film series, and was nominated for Best Short Form Music Video at the 2009 Grammy Awards, with director P. R. Brown. It was also nominated for Best Song at the 2008 Critics' Choice Awards, and won Best Original Song at the Satellite Awards 2008.

Quantum of Solace is a spy thriller film directed by Marc Forster, produced by Michael G. Wilson and Barbara Broccoli and written by Paul Haggis, Neal Purvis and Robert Wade. It is the 22nd film in the James Bond film series and stars Daniel Craig, Olga Kurylenko, Mathieu Amalric, Gemma Arterton, Jeffrey Wright and Judi Dench.