Laminated glass was invented in 1903 by French chemist Édouard Bénédictus (1878-1930), inspired by a laboratory accident. A glass flask had become coated with the plastic cellulose nitrate and when dropped shattered but did not break into pieces However, it was not until 1909 that Benedictus filed a patent. In 1911, he formed the Société du Verre Triplex, which fabricated a glass-plastic composite to reduce injuries in car accidents. Production of Triplex glass was slow and painstaking, making it expensive. It was not immediately widely adopted by automobile manufacturers, but laminated glass was widely used in the eyepieces of gas masks during World War I. In 1912, the process was licensed to The English Triplex Safety Glass Company. Subsequently, in the United States, both Libbey Owens-Ford and Du Pont de Nemours with Pittsburg Plate also licensed it.

Laminated glass is a type of safety glass that holds together when shattered. In the event of breaking, it is held in place by an interlayer, typically of polyvinyl butyral or ethylene-vinyl acetate between its two or more layers of glass. The interlayer keeps the layers of glass bonded even when broken, and its high strength prevents the glass from breaking up into large sharp pieces. This produces a characteristic "spider web" cracking pattern when the impact is not enough to completely pierce the glass.

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