The hectare is a non-SI metric unit of area equal to a square with 100-metre sides (1 hm2), or 10,000 m2, and is primarily used in the measurement of land. There are 100 hectares in one square kilometre. An acre is about 0.405 hectare and one hectare contains about 2.47 acres.

In 1795, when the metric system was introduced, the 'are' was defined as 100 square metres and the hectare ("hecto-" + "are") was thus 100 'ares' or 1⁄100 km2 (10,000 square metres). When the metric system was further rationalised in 1960, resulting in the International System of Units (SI), the are was not included as a recognised unit. The hectare, however, remains as a non-SI unit accepted for use with the SI and whose use is "expected to continue indefinitely".

More Info: en.wikipedia.org