Skunks are legendary for their powerful predator deterrent, a hard to remove & horrible smelling spray. A skunk's spray is an oily liquid produced by glands under its large tail. To employ this scent bomb, a skunk turns around and blasts its foe with a foul mist that can travel as far as ten feet (three meters). Interestingly, these animals cannot spray and bite simultaneously.

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More Info: en.wikipedia.org