The fastest spacecraft relative to the sun is the unmanned Helios 2 Probe, which achieved a speed of 252,792 kmph/157,078 mph on April 17, 1976. Helios 2 flew three million kilometers closer to the Sun than Helios 1, achieving perihelion on 17 April 1976 at a record distance of 0.29 AU (or 43.432 million kilometers), slightly inside the orbit of Mercury. Helios 2 was sent into orbit 13 months after the launch of Helios 1. The Helios space probes completed their primary missions by the early 1980s, but they continued to send data up to 1985. The probes are no longer functional but still remain in their elliptical orbit around the Sun.

More Info: en.wikipedia.org