What is the C-series paper size usually used for?

The C series is usually used for envelopes and is defined in ISO 269. The area of C series sheets is the geometric mean of the areas of the A and B series sheets of the same number; for instance, the area of a C4 sheet is the geometric mean of the areas of an A4 sheet and a B4 sheet. This means that C4 is slightly larger than A4, and slightly smaller than B4. The practical usage of this is that a letter written on A4 paper fits inside a C4 envelope, and both A4 and C4 paper fits inside a B4 envelope.

Some envelope formats with mixed sides from adjacent sizes (and thus an approximate aspect ratio of 2:1) are also defined in national adaptations of the ISO standard, e.g. DIN C6/C5 is 114 mm × 229 mm where the common side to C5 and C6 is 162 mm.