Psi is the 23rd and penultimate letter of the Greek alphabet and is associated with a numeric value of 700. In both Classical and Modern Greek, the letter indicates the combination "ps" (as in English word "lapse"). For Greek loanwords in Latin and modern languages with Latin alphabets, psi is usually transliterated as "ps".

The Greek alphabet has been used to write the Greek language since the late ninth or early eighth century BC. It is derived from the earlier Phoenician alphabet, and was the earliest known alphabetic script to have distinct letters for vowels as well as consonants.

In Archaic and early Classical times, the Greek alphabet existed in many local variants, but, by the end of the fourth century BC, the Euclidean alphabet, with twenty-four letters, ordered from alpha to omega, had become standard and it is this version that is still used for Greek writing today.

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